We demonstrate the band gap programming of inverse opals by fabrication of different wall thickness by atomic layer deposition (ALD). The opal templates were synthesized using polystyrene and carbon nanospheres by the vertical deposition method. The structure and properties of the TiO₂ inverse opal samples were investigated using Scanning Electron Microscope (SEM) and Focused Ion Beam Scanning Electron Microscopy (FIB-SEM), Energy Dispersive X-ray analysis (EDX), X-ray Diffraction (XRD) and Finite Difference Time Domain (FDTD) simulations. The photonic properties can be well detected by UV-Vis reflectance spectroscopy, while diffuse reflectance spectroscopy appears to be less sensitive. The samples showed visible light photocatalytic properties using Raman microscopy and UV-Visible spectrophotometry, and a newly developed digital photography-based detection method to track dye degradation. In our work, we stretch the boundaries of a working inverse opal to make it commercially more available while avoiding fully filling and using cheaper, but lower-quality, carbon nanosphere sacrificial templates.